Cut a circle of parchment paper that fits into a medium saucepan. Cut a small hole in the middle to allow the simple syrup to come to the top of the parchment. This will be used to submerge the pears. Set aside.
Add Water and Sugar to medium saucepan. Bring to a boil.
While the water is on to boil, prepare the Pears by peeling, quartering, and coring.
Using a vegetable peeler, peel the Orange, creating strips of peel.
Once water has boiled, reduce heat so that the liquid remains at a low simmer. Add the quartered Pears, Orange Peel, and Vanilla.
Lay the parchment paper circle on top of the Pears and submerge them.
Simmer gently for 15 minutes, until the pears are tender.
Remove from heat. Let pears cool in the liquid.